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Welcome Dr Sam Stranks, entrepreneur and professor at Cambridge University!
- Perovskites
- The family is based on the crystal structure
- Have been worked on for 2 to 3 decades
- Only since 2009 have they been used as a solar cell
- Sam’s background is physicist
- Raised in Australia
- Broad undergrad background
- Bridged chemistry and physics in Master’s program
- Worked on removing white wine proteins
- The mechanism is similar to how alzheimers blobs together
- 2007
- He got a Rhodes scholarship which meant he ended up going to Cambridge University.
- Research included carbon nanotubes
- Wrapping polymes around then
- Popularity has been dropping
- Fullerenes, Graphene both won Nobel prize.
- Producing nanotubes is difficult
- Dave made a video about a bunkum Kickstarter doing Graphene heaters
- Specifically separating out metallic and semiconductor types
- Finished PhD 2012
- Joined Henry Snaith‘s group doing dye sensitized solar cells
- Reemergence of perovskites
- The initial focus was on a dye sensitive cell made out of perovskite
- Early efficiency was 3%
- The research is done in a place that looks more like a chemistry lab than a semi lab
- Solar simulator to replicate the sun
- How are perovskites different from solar cells?
- Silicon has an indirect bandgap
- Multijunctions cells (the kind on satellites) have different absorbers (different colors)
- Record silicon efficiency is 27%
- Full panel is about 20%
- Perovskite is at 23%
- Triple junction is 39%
- Videos from past guests Sam Zeloof and Jeri Ellsworth
- Printed solar cells
- ABX3
- Thickness only needs to be half a micron
- The name ‘perovskite solar cell’ is derived from the ABX3 crystal structure of the absorber materials, which is referred to as perovskite structure. The most commonly studied perovskite absorber is methylammonium lead trihalide (CH3NH3PbX3, where X is a halogen atom such as iodine, bromine or chlorine), with an optical bandgap between 1.5 and 2.3 eV depending on halide content. Formamidinum lead trihalide (H2NCHNH2PbX3)
- Currently using Indium for the contact, but it’s hard to get, running out
- Talking through the stack
- Bottom electrode is Indium Tin oxide
- Then a layer of perovskite
- Top layer is organic
- Illumnate through the glass,
- InSnOx is transparent up to UV
- Perovskite absorbs 200-800
- Using lasers to test with pulses
- Pulses for a 1 ps
- Monitor how they recombine and lose energy
- What causes a defect?
- What actually makes electrons mobile in the ABX3 structure?
- Structure is mostly from the B and the X (lead and iodide)
- Covalently bonding vs ionic bonding
- Other applications being targeted
- Light emission (LEDs)
- Also using for lasing materials (LASERs)
- Want to make an electrically pumped laser
- Have been some changes in the A site that stabilize ion migration
- Sam is a founder of Swift Solar
- The 6 founders had spent time together in Henry Snaith’s group
- Focusing on making tandem cells
- Making a solar sheet
- More solar cells in a smaller area
- Payback periods
- Why hasn’t this started on the production side yet?
- Solar is coming down to 20 cent per watt
- Install costs are still $1 per watt
- The lightweight aspects lowers the cost of installation
- Sam did a TED talk
- Integrated photovoltaics
- Group web page
- Want to learn more about bandgaps? Check out pveducation.org
- Scientific American wrote an article about The Perovskite Boom last year
- Sam’s lab is taking new students! Reach him via his web page or reach out to him on Twitter (@SamStranks)
Photo: Ryan Lash / TED |